铜催化下由芳香醛一步合成芳香腈

章国林;胡永洲

引用本文:	章国林;胡永洲.铜催化下由芳香醛一步合成芳香腈[J].中国现代应用药学,2001,(1):45-46.
	Zhang Guolin(Zhang GL),Hu Yongzhou(Hu YZ).Copper-catalyzed one-pot conversion of aromatic aldehydes into aromatic nitriles[J].Chin J Mod Appl Pharm(中国现代应用药学),2001,(1):45-46.

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铜催化下由芳香醛一步合成芳香腈
章国林;胡永洲

作者	单位
章国林;胡永洲

摘要:

目的:改进芳香腈的合成方法。方法:以铜粉为催化剂,在NH4Cl、氧气存在下,将芳香醛一步转化为芳香腈。结果:利用此法合成了10个芳香腈,收率90 %～97%。结论:与文献方法比较,此法具原料易得,操作简单,收率高等特点。

关键词: 芳香醛芳香腈合成

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基金项目:

Copper-catalyzed one-pot conversion of aromatic aldehydes into aromatic nitriles

Zhang Guolin(Zhang GL),Hu Yongzhou(Hu YZ)

Abstract:

OBJECTIVE:To improve the synthesis of aromatic nitriles.METHOD:Aromatic aldehydes were converted into aromatic nitriles by the ammonium chloride,copper powder,oxygen system in pyridine.RESULTS:Ten aromatic nitriles were synthesized by this method.CONCLUSI

Key words: aromatic aldehyde,aromatic nitrile,synthesis